Organosulfur phosphonium salt-mediated synthesis of functionalized thiopyran derivatives.

Autor: Asghari, Sakineh, Firouzzade Pasha, Ghasem, Tajbakhsh, Mahmoud
Předmět:
Zdroj: Phosphorus, Sulfur & Silicon & the Related Elements; 2016, Vol. 191 Issue 6, p939-943, 5p
Abstrakt: Methyl 4-oxotetrahydro-2H-thiopyran-3-carboxylate as a CH-acid undergoes a mild reaction with acetylenic esters in the presence of triphenylphosphine to produce phosphorus ylides possessing thiopyran-4-one ring moiety. The resulted phosphorus ylides when heated in toluene afforded functionalized thiopyran derivatives through intramolecular Wittig reaction. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index