| Autor: |
An, Dong, Guan, Xukai, Guan, Rui, Jin, Lajiao, Zhang, Guangliang, Zhang, Suoqin |
| Předmět: |
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| Zdroj: |
Chemical Communications; 9/28/2016, Vol. 52 Issue 75, p11211-11214, 4p |
| Abstrakt: |
The first organocatalytic asymmetric nucleophilic addition of arylpyrazoles to 2H-azirines and kinetic resolution of racemic 2H-azirines have been realized. Chiral aziridines were obtained with up to 98% yields and up to 99.9% ee. Meanwhile, simply changing the ratio of reactants, optically active 2H-azirines were recovered in good yields with excellent enantioselectivities. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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