| Autor: |
Li, Jiangnan, Jiang, Shende, Procopiou, George, Stockman, Robert A., Yang, Guang |
| Předmět: |
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| Zdroj: |
European Journal of Organic Chemistry; Jul2016, Vol. 2016 Issue 21, p3500-3504, 5p |
| Abstrakt: |
The first diastereoselective allylation reaction at the α-position of ketones by using tert-butanesulfinamide as a chiral auxiliary is explored. Excellent yields and high diastereomeric ratios were achieved under palladium catalysis in the presence of a readily available achiral phosphine ligand. The chiral auxiliary was removed in quantitative yield under the optimized conditions without any racemization. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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