Palladium-Catalyzed Direct Benzylation of Polyfluoroarenes with Benzyl Carbonates through Selective C−H Functionalization.

Autor: Yang, Guanghui, Jiang, XinpENg, Liu, Yong, Li, Na, Yin, GuisEN, Yu, Chuanming
Předmět:
Zdroj: Asian Journal of Organic Chemistry; Jul2016, Vol. 5 Issue 7, p882-885, 4p
Abstrakt: A novel and efficient palladium-catalyzed cross-coupling benzylation reaction of pentafluorobenzene through selective C−H functionalization has been developed. A series of carbonates and polyfluorobenzenes have been examined and found to give moderate to good yields. This transformation provides a new straightforward approach for the synthesis of fluorinated diarylmethanes. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index