| Autor: |
Banger, Kulbinder K., Duraj, Stan A., Fanwick, Philip E., Hehemann, David G., Hepp, Aloysius F., Martuch, Robert A. |
| Předmět: |
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| Zdroj: |
Journal of Coordination Chemistry; 12/1/2002, Vol. 55 Issue 12, p1427-1431, 5p, 1 Diagram, 2 Charts |
| Abstrakt: |
The synthesis and structural characterization of a novel In(III) complex is described. The reaction between InCl 3 with sodium mercapto-acetic acid (NaSCH 2 (CO)OH) in 4-methylpyridine (CH 3 (C 5 H 5 N), (4-Mepy)) at 25°C affords [ClIn(SCH 2 (CO)O) 2 ] 2- [(4-MepyH) 2 ] 2+ (1) . X-ray diffraction studies of (1) show it to have a distorted square-pyramidal geometry with the [( - SCH 2 (CO)CO - )] ligands in a trans conformation. The compound crystallizes in the $ \bar P1 $ (No. 2) space group with a = 7.8624(6) Å, b = 9.950(1) Å, c = 13.793(2) Å, α = 107.60(1)°, β = 90.336(8)°, γ = 98.983(9)°, V = 1014.3(4) Å 3 , R (F°) = 0.037 and R w = 0.048. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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