| Autor: |
Starosotnikov, Alexey M., Nikol'skiy, Vladislav V., Borodulya, Anastasiya N., Kachala, Vadim V., Bastrakov, Maxim A., Solkan, Vitaly N., Shevelev, Svyatoslav A. |
| Předmět: |
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| Zdroj: |
Asian Journal of Organic Chemistry; May2016, Vol. 5 Issue 5, p685-690, 6p |
| Abstrakt: |
An efficient method was developed for the synthesis of 5,7-dinitroquinoline and its N-oxide. The reactions of these compounds with either thiols or sodium azide resulted in the regiospecific substitution of 5-NO2 group and the formation of previously unknown quinoline derivatives. The 5-azido derivatives underwent reactions with 1,3-dicarbonyl compounds and, depending on the nature of reagent, afforded either 5-(1,2,3-triazol)-1-yl- or 5-amino-7-nitroquinolines, which have been previously inaccessible by using other methods. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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