Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride.

Autor:	Kameo, H., Ikeda, K., Sakaki, S., Takemoto, S., Nakazawa, H., Matsuzaka, H.
Předmět:	IRIDIUM hydrides SILICON compounds CHEMICAL synthesis CHLORINE GERMANIUM chlorides CHEMICAL bonds
Zdroj:	Dalton Transactions: An International Journal of Inorganic Chemistry; 5/14/2016, Vol. 45 Issue 18, p7570-7580, 11p
Abstrakt:	We report the iridium hydride-mediated Si–Cl and Ge–Cl σ-bond activation in a low-polarity toluene solution owing to diphosphine-chelation, in which the Si–Cl and Ge–Cl σ-bonds are readily cleaved through an SN2-type pathway via the formation of a free chloride anion. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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