Co and Cu co-doped ZnO epitaxial films--A magnetically soft nano-composite.

Autor: Ney, V., Venkataraman, V., Henne, B., Ollefs, K., Wilhelm, F., Rogalev, A., Ney, A.
Předmět:
Zdroj: Journal of Applied Physics; 4/28/2016, Vol. 119 Issue 16, p1-7, 7p, 7 Graphs
Abstrakt: A series of Co/Cu co-doped ZnO epitaxial films has been grown on sapphire substrates to investigate the possibilities of tailoring the magnetic properties in functional ZnO-Co/Cu nano-composites. The growth was performed using reactive magnetron sputtering varying the oxygen partial pressure to tune the incorporation of the dopants and the resulting valence state. At high oxygen pressures, Co2+ is formed and the resulting magnetic properties are very similar to phase pure paramagnetic Co-doped ZnO samples. However, the formation of a secondary CuO phase reduces the overall structural quality of the layers and virtually no substitutional incorporation of Cu2+ in ZnO could be evidenced. At low oxygen pressures, a significant fraction of metallic Co and Cu forming nanometer-sized superparamagnetic precipitates of a Co/Cu alloy can be evidenced which are embedded in a ZnO host matrix. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index