| Autor: |
Tsudaka, Takeshi, Ohkubo, Kei, Fukuzumi, Shunichi |
| Předmět: |
|
| Zdroj: |
Chemical Communications; 5/4/2016, Vol. 52 Issue 36, p6178-6180, 3p |
| Abstrakt: |
Photocatalytic oxidation of iron(ii) complexes by dioxygen occurred using the organic photocatalysts, 9-mesityl-10-methylacridinium ions (Acr+-Mes) and 2-phenyl-4-(1-naphthyl) quinolinium ions (QuPh+-NA), in the presence of triflic acid in acetonitrile under visible light irradiation. The electron-transfer state of Acr+-Mes produced upon photoexcitation oxidized the iron(ii) complexes, whereas it reduced dioxygen with protons to produce iron(iii) complexes and H2O2. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
