| Autor: |
Bhattacharyya, Koyel X., Dreyfuss, Sébastien, Saffon-Merceron, Nathalie, Mézailles, Nicolas |
| Předmět: |
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| Zdroj: |
Chemical Communications; 4/14/2016, Vol. 52 Issue 29, p5179-5182, 4p |
| Abstrakt: |
A direct method for white phosphorus functionalization by hydride sources is presented. Excess BH4− in n-butylamine produces HP4− as the major P-containing species. Reaction with LiBEt3H forms the borane-stabilized phosphanide Li(PH2)(BEt3)2, which may be used to synthesize various phosphines. Triethylborane may be replaced by BH3, resulting in the formation of LiPH2(BH3)2. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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