Tandem photovoltaic–photoelectrochemical GaAs/InGaAsP–WO3/BiVO4 device for solar hydrogen generation.

Autor: Sonya Kosar, Yuriy Pihosh, Ivan Turkevych, Kazuma Mawatari, Jin Uemura, Yutaka Kazoe, Kikuo Makita, Takeyoshi Sugaya, Takuya Matsui, Daisuke Fujita, Masahiro Tosa, Yaroslav M. Struk, Michio Kondo, Takehiko Kitamori
Zdroj: Japanese Journal of Applied Physics; Apr2016, Vol. 55 Issue 4s, p1-1, 1p
Abstrakt: We demonstrated highly efficient solar hydrogen generation via water splitting by photovoltaic–photoelectrochemical (PV–PEC) tandem device based on GaAs/InGaAsP (PV cell) and WO3/BiVO4 core/shell nanorods (PEC cell). We utilized extremely thin absorber (ETA) concept to design the WO3/BiVO4 core/shell heterojunction nanorods and obtained the highest efficiencies of generation, separation and transfer of the photo-induced charge carriers that are possible for the WO3/BiVO4 material combination. The PV–PEC tandem shows stable water splitting photocurrent of 6.56 mA·cm−2 under standard AM1.5G solar light that corresponds to the record solar-to-hydrogen (STH) conversion efficiency of 8.1%. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index