Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle.

Autor: Bergemann, N., Pistidda, C., Milanese, C., Emmler, T., Karimi, F., Chaudhary, A.-L., Chierotti, M. R., Klassen, T., Dornheim, M.
Předmět:
Zdroj: Chemical Communications; 4/4/2016, Vol. 52 Issue 26, p4836-4839, 4p
Abstrakt: The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index