| Autor: |
Lupeiko, T.G., Chirkova, D.V., Lisnevskaya, I.V. |
| Předmět: |
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| Zdroj: |
Ferroelectrics; 2016, Vol. 493 Issue 1, p183-190, 8p |
| Abstrakt: |
The possibility to synthesize SbSBr and SbSI1-xBrxin a dilute hydrochloric acid solution was shown. Conversely to the SbSI, synthesis of SbSBr and SbSI1-xBrxin this solution requires an excess of bromide-anions, higher temperature and prolonged duration of chemical reaction. The final products were characterized by X-ray diffraction, X-ray fluorescence, energy-dispersive X-ray spectroscopy, scanning electron microscopy and iodometric titration measurements. The real content of bromide in the resulting SbSI1-xBrxphases is less than the bromide amount calculated according to the reaction equation due to the lower π-acceptor properties of bromide as compared with iodide. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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