Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de α-metileno-γ-butirolactonas Monoterpênicas.

Autor: Bezerra dos Santos, Reginaldo, Vettoraci César, Roberta Cecília, Lacerda Jr., Valdemar, Greco, Sandro José, Neto, Alvaro Cunha
Zdroj: Orbital: The Electronic Journal of Chemistry; Oct-Dec2015, Vol. 7 Issue 4, p396-400, 6p
Abstrakt: (R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural α-methylene-γ-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control of regio selectivity and stereo selectivity. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index