| Autor: |
Perotto, Carlo U., Marshall, George, Jones, Graham J., Stephen Davies, E., Lewis, William, McMaster, Jonathan, Schröder, Martin |
| Předmět: |
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| Zdroj: |
Chemical Communications; 12/11/2015, Vol. 51 Issue 95, p16988-16991, 4p |
| Abstrakt: |
[Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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