Synthesis and characterization of a trans-1 hexakis-fullerene linker that forms crystalline polymers with silver salts.

Autor: Chen, Chia-Hsiang, Aghabali, Amineh, Metta-Magana, Alejandro J., Olmstead, Marilyn M., Balch, Alan L., Echegoyen, Luis
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/14/2015, Vol. 44 Issue 42, p18487-18491, 5p
Abstrakt: A new flexible hexakis-fullerene adduct with two bis(pyridin-4-ylmethyl)malonate groups located at trans-1 positions was synthesized. Via reaction with Ag(PF6) under two different conditions, two new 1D coordination polymers were obtained; under a nitrogen atmosphere, the silver ions are connected by argentophilic interactions but under an ambient atmosphere, the silver ions exhibit no interaction between them but coordination to the (H2PO4) ions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index