Synthesis and Study of Head-to-Tail Regioregular Poly(alkyl thiophene-3-carboxylates­).

Autor: Amarasekara, Ananda S., Pomerantz, Martin
Předmět:
Zdroj: Synthesis; Oct2003, Vol. 2003 Issue 14, p2255-2258, 4p
Abstrakt: Regioregular head-to-tail poly(alkyl thiophene-3-carboxylates) have been prepared by very careful formation of the mono-Grignard reagent from alkyl 2,5-dibromothiophene-3-carboxylates (-40 °C, 1 h) followed by nickel-catalyzed polymerization. The spectral properties are reported along with the molecular weights. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index