| Autor: |
Esteves-López, Natalia, Dedonder-Lardeux, Claude, Jouvet, Christophe |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 2015, Vol. 143 Issue 7, p1-5, 5p, 2 Diagrams, 2 Graphs |
| Abstrakt: |
We present photo-fragmentation electronic spectra of the simplest protonated aromatic molecules, protonated benzene and toluene, recorded under medium resolution conditions and compared with the photo-fragmentation spectrum of protonated pyridine. Despite the resolution and cold temperature achieved in the experiment, the electronic spectra of protonated benzene and toluene are structure-less, thus intrinsically broadened. This is in agreement with the large geometrical changes and the fast dynamic toward internal conversion predicted by ab initio calculations for protonated benzene. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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