| Autor: |
Mejorado, Lupe, Pettus, Thomas R. R. |
| Předmět: |
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| Zdroj: |
Synthesis; 2006, Vol. 2006 Issue 19, p3209-3214, 6p |
| Abstrakt: |
A route enabling the synthesis of the stereo-triad of rishirilide B (1) from 2-hydroxy-3-methylnaphthalene-1,4-dione, is reported. Key transformations include the regioselective 1,2-Grignard addition to a tautomeric mixture of o- and p-quinones, regioselective carbamoylation of a tautomeric mixture, and a synopsis of the methods explored to convert various terminal vinyl ethers into the corresponding carboxylic acid by cleavage. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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