| Autor: |
Thi Vo, Venkatasubramanian, Venkat, Kumar, Sanat, Srinivasan, Babji, Pal, Suchetan, Yugang Zhang, Gang, Oleg |
| Předmět: |
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| Zdroj: |
Proceedings of the National Academy of Sciences of the United States of America; 4/21/2015, Vol. 112 Issue 16, p4982-4987, 6p |
| Abstrakt: |
There has been considerable interest in understanding the selfassembly of DNA-grafted nanoparticles into different crystal structures, e.g., CsCl, AlB2, and Cr3Si. Although there are important exceptions, a generally accepted view is that the right stoichiometry of the two building block colloids needs to be mixed to form the desired crystal structure. To incisively probe this issue, we combine experiments and theory on a series of DNA-grafted nanoparticles at varying stoichiometries, including noninteger values. We show that stoichiometry can couple with the geometries of the building blocks to tune the resulting equilibrium crystal morphology. As a concrete example, a stoichiometric ratio of 3:1 typically results in the Cr3Si structure. However, AlB2 can formwhen appropriate building blocks are used so that the AlB2 standard-state free energy is low enough to overcome the entropic preference for Cr3Si. These situations can also lead to an undesirable phase coexistence between crystal polymorphs. Thus, whereas stoichiometry can be a powerful handle for direct control of lattice formation, care must be taken in its design and selection to avoid polymorph coexistence. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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