| Autor: |
Jayaraman, Arumugam, Jacob, Tyler V., Bisskey, Jeff, Sterenberg, Brian T. |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 5/21/2015, Vol. 44 Issue 19, p8788-8791, 4p |
| Abstrakt: |
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P–C bond formation. This methodology can be applied sequentially two or three times, stepwise or in one-pot reactions, to form phosphines with three different substituents. The reactions are rapid and high-yielding, and can be applied to a wide range of organic substrates, making them valuable tools for P–C bond formation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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