| Autor: |
Gieshoff, Tim N., Villa, Matteo, Welther, Alice, Plois, Markus, Chakraborty, Uttam, Wolf, Robert, Jacobi von Wangelin, Axel |
| Předmět: |
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| Zdroj: |
Green Chemistry; 2015, Vol. 17 Issue 3, p1408-1413, 6p |
| Abstrakt: |
The scope and mechanism of a practical protocol for the iron-catalyzed hydrogenation of alkenes and alkynes at 1 bar H2 pressure were studied. The catalyst is formed from cheap chemicals (5 mol% FeCl3–LiAlH4, THF). A homogeneous mechanism operates at early stages of the reaction while active nanoparticles form upon ageing of the catalyst solution. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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