| Autor: |
Concepcion, Javier J., Zhong, Diane K., Szalda, David J., Muckerman, James T., Fujita, Etsuko |
| Předmět: |
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| Zdroj: |
Chemical Communications; 2015, Vol. 51 Issue 19, p4105-4108, 4p |
| Abstrakt: |
We describe here a combined solution-surface-DFT calculations study for complexes of the type [Ru(bda)(L)2] including X-ray structure of intermediates and their reactivity, as well as pH-dependent electrochemistry and spectroelectrochemistry. These studies shed light on the mechanism of water oxidation by [Ru(bda)(L)2], revealing key features unavailable from solution studies with sacrificial oxidants. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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