Ruthenium(II)-Catalyzed CH Arylation of Anilides with Boronic Acids, Borinic Acids and Potassium Trifluoroborates.

Autor:	Hubrich, Jonathan, Himmler, Thomas, Rodefeld, Lars, Ackermann, Lutz
Předmět:	RUTHENIUM catalysts ARYLATION ANILIDES BORONIC acids ANILIDE synthesis
Zdroj:	Advanced Synthesis & Catalysis; Feb2015, Vol. 357 Issue 2/3, p474-480, 7p
Abstrakt:	An in situ generated cationic ruthenium(II) catalyst allowed for robust CH arylations of anilides with boronic acids. The optimized ruthenium catalyst was found to be both site selective and chemoselective, thereby providing the monoarylated products in excellent yields with ample substrate scope. The catalyst's high efficacy furthermore set the stage for efficient CH arylations with borinic acids as well as potassium trifluoroborates. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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