A stable Li-deficient oxide as high-performance cathode for advanced lithium-ion batteries.

Autor: Hou, Peiyu, Wang, Jie, Song, Jishun, Song, Dawei, Shi, Xixi, Wang, Xiaoqing, Zhang, Lianqi
Předmět:
Zdroj: Chemical Communications; 2015, Vol. 51 Issue 15, p3231-3234, 4p
Abstrakt: Monodisperse Li-deficient Li0.35Ni0.2Co0.1Mn0.7O2−x spinel single crystals have been prepared for the first time. The Li-deficient oxide surprisingly delivers large reversible capacity (251.3 mA h g−1), outstanding cycle life and low median-voltage of 2.7 V in the range of 2.0–4.9 V. Importantly, high median-voltage (4.4 V) and superior rate capability are also obtained from 3.0 to 5.0 V. These results indicate that high-energy or high-power density can be achieved by controlling discharge cut-off voltage. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index