| Autor: |
Zhang, Min, Zhao, Xiaoming, Zheng, Shengcai |
| Předmět: |
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| Zdroj: |
Chemical Communications; 2014, Vol. 50 Issue 34, p4455-4458, 4p |
| Abstrakt: |
The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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