Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons.
| Autor: | Lewis, Richard A., MacLeod, K. Cory, Mercado, Brandon Q., Holland, Patrick L. |
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| Zdroj: | Chemical Communications; 2014, Vol. 50 Issue 76, p11114-11117, 4p |
| Abstrakt: | A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C-C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η¹:η³ binding mode. [ABSTRACT FROM AUTHOR] |
| Databáze: | Complementary Index |
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