C60 fullerenol as an active and stable catalyst for the synthesis of cyclic carbonates from CO2 and epoxides.

Autor: Yong-Bin Sun, Chang-Yan Cao, Shu-Liang Yang, Pei-Pei Huang, Chun-Ru Wang, Wei-Guo Song
Předmět:
Zdroj: Chemical Communications; 2014, Vol. 50 Issue 71, p10307-10310, 4p
Abstrakt: C60 fullerenol was found to be a highly active, selective and stable catalyst for cycloaddition between CO2 and epoxides to produce various cyclic carbonates with excellent yields (89-99%). A solid/ liquid interfacial hydrogen-bond assisted mechanism was proposed to account for its high efficiency. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index