| Autor: |
Abi-Ghaida, Fatima, Laila, Zahra, Ibrahim, Ghassan, Naoufal, Daoud, Mehdi, Ahmad |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 2014, Vol. 43 Issue 34, p13087-13095, 9p |
| Abstrakt: |
Novel silylated hydroborate clusters comprising the closo-decaborate cage were prepared and characterized by ¹H, 13C, 11B, 29Si NMR and mass spectroscopy ESI. The synthesis of such silylated clusters was achieved using reactive derivatives of [B10H10]2-, [1-B10H9N2]- and [2-B10H9CO]-. These silylated decaborate clusters constitute a new class of precursors that can be covalently anchored onto various silica supports without any prior surface modification. As a proof of concept, the synthesized precursors were successfully anchored on mesoporous silica, SBA-15 type, in different percentages, where the mesoporous material retained its structure. All materials modified with closo-decaborate were characterized by 11B and 29Si solid state NMR, XRD, TEM and nitrogen sorption. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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