4-Keto-bacteriorhodopsin films as a promising photochromic and electrochromic biological material.

Autor: Druzhko AB; Institute of Theoretical and Experimental Biophysics, Pushchino, Moscow Region, Russia., Chamorovsky SK, Lukashev EP, Kononenko AA, Vsevolodov NN
Jazyk: angličtina
Zdroj: Bio Systems [Biosystems] 1995; Vol. 35 (2-3), pp. 129-32.
DOI: 10.1016/0303-2647(94)01499-w
Abstrakt: Photochromic and electrochromic spectral properties of 4-keto-bacteriorhodopsin (4-keto-BR) embedded in a polymer matrix were studied. The light-induced spectral changes were found to be similar to those for 4-keto-BR in suspension, but the duration of the photocycle is substantially longer (up to ten of h). Application of a constant electric field induces a bathochromic shift of the main absorption band, the amplitude of the field-induced spectral changes, showing a quadratic dependence on the field strength. Polymer films containing bacteriorhodopsin analogs show promise as new spectrally-selective photochromic and electrochromic materials.
Databáze: MEDLINE