Synthesis, crystal structure and Hirshfeld surface analysis of (2-amino-1-methyl-benzimidazole-κ N 3 )aqua-bis-(4-oxopent-2-en-2-olato-κ 2 O , O ')nickel(II) ethanol monosolvate.

Autor: Siddikova K; Karshi Engineering Economics Institute, Mustakillik Avenue, 225, Karshi 180100, Uzbekistan., Sardor M; National University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan.; Uzbekistan-Japan Innovation Centre of Youth, University Street 2B, Tashkent 100095, Uzbekistan., Tojiboyev A; University of Geological Sciences, Olimlar Street, 64, Tashkent 100170, Uzbekistan., Kadirova Z; National University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan.; Uzbekistan-Japan Innovation Centre of Youth, University Street 2B, Tashkent 100095, Uzbekistan., Ashurov J; Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo, Ulugbek Street 83, Tashkent 100125, Uzbekistan., Daminova S; National University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan.; Uzbekistan-Japan Innovation Centre of Youth, University Street 2B, Tashkent 100095, Uzbekistan.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2024 Oct 22; Vol. 80 (Pt 11), pp. 1186-1189. Date of Electronic Publication: 2024 Oct 22 (Print Publication: 2024).
DOI: 10.1107/S2056989024008958
Abstrakt: The mol-ecule of the title compound, [Ni(C 5 H 7 O 2 ) 2 (C 8 H 9 N 3 )(H 2 O)]·C 2 H 5 OH, has triclinic ( P ) symmetry. This compound is of inter-est for its anti-microbial properties. The asymmetric unit comprises two independent complex mol-ecules, which are linked by N-H⋯O and O-H⋯O hydrogen bonds along [111]. Hirshfeld surface analysis indicates that 71.7% of inter-mol-ecular inter-actions come from H⋯H contacts, 17.7% from C⋯H/H⋯C contacts and 7.6% from O⋯H/H⋯O contacts, with the remaining contribution coming from N⋯H/H⋯N, C⋯N/N⋯C, C⋯C and O⋯O contacts.
(© Siddikova et al. 2024.)
Databáze: MEDLINE
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