Holistic Thermo-Optical Design of Laminate Layers for Halide Perovskite Photovoltaic Windows.

Autor:	Prince KJ; National Renewable Energy Laboratory, Golden, Colorado 80401, United States.; Department Chemical and Biological Engineering, Colorado School of Mines, Golden, Colorado 80401, United States., Irvin NP; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Mirzokarimov M; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Rosales BA; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Moore DT; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Guthrey HL; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Palmstrom AF; National Renewable Energy Laboratory, Golden, Colorado 80401, United States., Wolden CA; National Renewable Energy Laboratory, Golden, Colorado 80401, United States.; Department Chemical and Biological Engineering, Colorado School of Mines, Golden, Colorado 80401, United States., Wheeler LM; National Renewable Energy Laboratory, Golden, Colorado 80401, United States.
Jazyk:	angličtina
Zdroj:	ACS energy letters [ACS Energy Lett] 2024 Nov 11; Vol. 9 (12), pp. 5836-5849. Date of Electronic Publication: 2024 Nov 11 (Print Publication: 2024).
DOI:	10.1021/acsenergylett.4c02017
Abstrakt:	Though power conversion is an important metric for photovoltaic windows, it must be balanced with visible transmittance, aesthetics (color and haze), and thermal performance. Optical properties are often reported, but thermal performance is typically neglected entirely in photovoltaic window design. Here, we introduce the strategy of using laminate layers to improve the thermo-optical performance of perovskite-based photovoltaic insulating glass units. We design the laminates and insulating glass units by coupling a transfer matrix method optical model to a 1D heat transfer model. We validate our models with experimental fabrication of one-dimensional photonic crystal layers that are deposited on glass and laminated to the perovskite photovoltaic device. The holistic designs neutralize the inherent transmissive red color, and the "red low-e" design dramatically reduce emissivity of the glass surface to significantly improve thermal insulation and boost the photocurrent of the device. Competing Interests: The authors declare no competing financial interest. (© 2024 The Authors. Published by American Chemical Society.)
Databáze:	MEDLINE
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