Mechanistic Insights and Technical Challenges in Sulfur-Based Batteries: A Comprehensive In Situ / Operando Monitoring Toolbox.

Autor:	Yu J; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Barcelona 08193, Spain.; Catalonia Institute for Energy Research (IREC), Barcelona 08930, Spain., Pinto-Huguet I; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Barcelona 08193, Spain., Zhang CY; School of Physical Science & Technology, Lanzhou University, Lanzhou 730000, China., Zhou Y; Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, National Engineering Research Center for Marine Aquaculture, Marine Science and Technology College, Zhejiang Ocean University, Zhoushan, Zhejiang Province 316004, China., Xu Y; Department of Applied Physics, Aalto University, Espoo 00076, Finland.; Institute of Electrochemical Energy Storage, Helmholtz-Zentrum Berlin für Materialien und Energie, Berlin 14109, Germany., Vizintin A; National Institute of Chemistry, Ljubljana 1000, Slovenia., Velasco-Vélez JJ; ALBA Synchrotron, Barcelona 08290, Spain., Qi X; College of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China., Pan X; State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China., Oney G; Univ. Grenoble Alpes, CEA, CNRS, Grenoble INP, IRIG, SYMMES, Grenoble 38000, France., Olgo A; Univ. Grenoble Alpes, CEA, CNRS, Grenoble INP, IRIG, SYMMES, Grenoble 38000, France., Märker K; Univ. Grenoble Alpes, CEA, IRIG, MEM, Grenoble 38000, France., M Da Silva L; Department of Chemistry, Federal University of Jequitinhonha e Mucuri, Diamantina 39100-000, Brazil., Luo Y; Department of Applied Biology and Chemical Technology, Hong Kong Polytechnic University, Hong Kong, China., Lu Y; Institute of Electrochemical Energy Storage, Helmholtz-Zentrum Berlin für Materialien und Energie, Berlin 14109, Germany., Huang C; Catalonia Institute for Energy Research (IREC), Barcelona 08930, Spain.; Department of Chemistry, University of Barcelona, Barcelona 08028, Spain., Härk E; Institute of Electrochemical Energy Storage, Helmholtz-Zentrum Berlin für Materialien und Energie, Berlin 14109, Germany., Fleming J; Centre for E-Mobility and Clean Growth, Coventry University, Coventry CV1 5FB, United Kingdom., Chenevier P; Univ. Grenoble Alpes, CEA, CNRS, Grenoble INP, IRIG, SYMMES, Grenoble 38000, France., Cabot A; Catalonia Institute for Energy Research (IREC), Barcelona 08930, Spain.; ICREA, Pg. Lluis Company, 08010 Barcelona, Spain., Bai Y; State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China., Botifoll M; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Barcelona 08193, Spain., Black AP; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Barcelona 08193, Spain., An Q; School of Materials and Energy, Yunnan University, Kunming 650091, China., Amietszajew T; Centre for E-Mobility and Clean Growth, Coventry University, Coventry CV1 5FB, United Kingdom., Arbiol J; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Barcelona 08193, Spain.; ICREA, Pg. Lluis Company, 08010 Barcelona, Spain.
Jazyk:	angličtina
Zdroj:	ACS energy letters [ACS Energy Lett] 2024 Dec 04; Vol. 9 (12), pp. 6178-6214. Date of Electronic Publication: 2024 Dec 04 (Print Publication: 2024).
DOI:	10.1021/acsenergylett.4c02703
Abstrakt:	Batteries based on sulfur cathodes offer a promising energy storage solution due to their potential for high performance, cost-effectiveness, and sustainability. However, commercial viability is challenged by issues such as polysulfide migration, volume changes, uneven phase nucleation, limited ion transport, and sluggish sulfur redox kinetics. Addressing these challenges requires insights into the structural, morphological, and chemical evolution of phases, the associated volume changes and internal stresses, and ion and polysulfide diffusion within the battery. Such insights can only be obtained through real-time reaction monitoring within the battery's operational environment, supported by molecular dynamics simulations and advanced artificial intelligence-driven data analysis. This review provides an overview of in situ/operando techniques for real-time tracking of these processes in sulfur-based batteries and explores the integration of simulations with experimental data to provide a holistic understanding of the critical challenges, enabling advancements in their development and commercial adoption. Competing Interests: The authors declare no competing financial interest. (© 2024 The Authors. Published by American Chemical Society.)
Databáze:	MEDLINE
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