Polyoxometalates as advanced-performance anions for ∼ D 5h Dy(III) single-ion magnets.
| Autor: | Lowe E; School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. tsanai.angelos@gmail.com., Wilson C; School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. tsanai.angelos@gmail.com., Canaj AB; School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. tsanai.angelos@gmail.com., Murrie M; School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. tsanai.angelos@gmail.com. |
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| Jazyk: | angličtina |
| Zdroj: | Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2024 Dec 10. Date of Electronic Publication: 2024 Dec 10. |
| DOI: | 10.1039/d4dt02877e |
| Abstrakt: | We enhance single-ion magnet (SIM) magnetisation reversal barriers by engineering the second coordination sphere, substituting conventional small monoanions with a bulky polyoxometalate (POM) trianion. Importantly, our approach serves as a model for creating new high-performance multifunctional hybrid materials. |
| Databáze: | MEDLINE |
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