Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films.

Autor: Oyetunde T; Department of Chemical Sciences, Faculty of Natural Sciences, Redeemer's University, P.M.B. 230, Ede, 232102, Nigeria.; School of Chemistry and School of Materials, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK., Omorogie MO; Department of Chemical Sciences, Faculty of Natural Sciences, Redeemer's University, P.M.B. 230, Ede, 232102, Nigeria.; Water Science and Technology Research Unit, African Centre of Excellence for Water and Environmental Research, Redeemer's University, P.M.B. 230, Ede, 232102, Nigeria.; Chair of Urban Water Systems Engineering, School of Engineering and Design, Technical University of Munich, Garching, 85748, Germany., O'Brien P; School of Chemistry and School of Materials, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Jazyk: angličtina
Zdroj: ChemistryOpen [ChemistryOpen] 2024 Dec 04, pp. e202400295. Date of Electronic Publication: 2024 Dec 04.
DOI: 10.1002/open.202400295
Abstrakt: Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EP i Pr 2 ) 2 N} 2 ], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'P i Pr 2 NH)] (E, E'=Se, Se; S, Se). These complexes were characterized and used as single-source precursors through Aerosol-Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm). The morphology of the deposited films ranged between dense fibrous network and woven fibres. X-ray photoelectron spectroscopy (XPS) confirmed the presence of the constituent elements in zinc selenide.
(© 2024 The Authors. ChemistryOpen published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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