Single-Pass Demonstration of Integrated Capture and Catalytic Conversion of CO 2 from Simulated Flue Gas to Methanol in a Water-Lean Carbon Capture Solvent.

Autor: Barpaga D; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., King JA; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Kothandaraman J; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Lopez JS; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Moskowitz BM; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Hubbard ML; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Zheng RF; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Malhotra D; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Koech PK; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Zwoster AJ; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Dagle RA; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States., Heldebrant DJ; Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States.
Jazyk: angličtina
Zdroj: ACS omega [ACS Omega] 2024 Nov 04; Vol. 9 (46), pp. 46247-46262. Date of Electronic Publication: 2024 Nov 04 (Print Publication: 2024).
DOI: 10.1021/acsomega.4c06919
Abstrakt: Here, we demonstrate an integrated semibatch simultaneous CO 2 capture and conversion to methanol process using a water-lean solvent, N -(2-ethoxyethyl)-3-morpholinopropan-1-amine (2-EEMPA), that serves as both the capture solvent and subsequent condensed-phase medium for the catalytic hydrogenation of CO 2 . CO 2 is captured from simulated coal-derived flue gas at a target >90 mol % capture efficiency, with a continuous slipstream of CO 2 -rich solvent delivered to a fixed bed catalytic reactor for catalytic hydrogenation. A single-pass conversion rate >60 C-mol % and selectivity >80 C-mol % are observed for methanol at relatively low temperatures (<200 °C) in the condensed phase of the carbon capture solvent. Hydrogenation products also include higher alcohols (e.g., ethanol and propanol) and hydrocarbons (e.g., methane and ethane), suggesting that multiple products could be made offering adaptability with varied CO 2 -derived products. Catalyst activity and selectivity are directly impacted by the water content in the capture solvent. Anhydrous operation provides high catalyst activity and productivity, suggesting that water management will be a critical parameter in real-world operation. Ultimately, we conclude that the integrated capture and catalytic hydrogenation of CO 2 are chemically viable and potentially more energetically efficient and cost-effective than conventional separate capture and conversion approaches.
Competing Interests: The authors declare no competing financial interest.
(© 2024 The Authors. Published by American Chemical Society.)
Databáze: MEDLINE