| Autor: |
Zhao R, Lv X, Yang HR, Gao L, Zhou L, Fang S, Liu SL |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 2024 Dec 06; Vol. 89 (23), pp. 17844-17849. Date of Electronic Publication: 2024 Nov 20. |
| DOI: |
10.1021/acs.joc.4c02236 |
| Abstrakt: |
The Rh(III)-catalyzed indole C4-H bond addition to nitroalkenes is disclosed under mild and redox-neutral reaction conditions, offering straightforward access to various 4-(2-nitroalkyl)indoles (34 examples) with excellent chemo- and regioselectivity. Furthermore, late-stage diversifications and mechanistic studies were also performed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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