Enhanced removal of methyl orange and malachite green using mesoporous TO@CTAB nanocomposite: Synthesis, characterization, optimization and real wastewater treatment efficiency.

Autor: Sharma A; Department of Environmental Science and Engineering, Guru Jambheshwar University of Science & Technology, Hisar, 125001, Haryana, India. anujvashist2511@gmail.com.; Department of Applied Science and Humanities, ITS Engineering College, Greater Noida, 201310, Uttar Pradesh, India. anujvashist2511@gmail.com., Mona S; Department of Environmental Studies, School of Interdisciplinary and Applied Sciences, Central University of Haryana, Mahendergarh, 123031, Haryana, India., Sharma P; Department of Environmental Science and Engineering, Guru Jambheshwar University of Science & Technology, Hisar, 125001, Haryana, India. ps.enbt@gmail.com.
Jazyk: angličtina
Zdroj: Environmental monitoring and assessment [Environ Monit Assess] 2024 Nov 19; Vol. 196 (12), pp. 1219. Date of Electronic Publication: 2024 Nov 19.
DOI: 10.1007/s10661-024-13304-8
Abstrakt: This study explores the synthesis of a novel titanium oxide-cetyltrimethylammonium bromide (TO@CTAB) nanocomposite for the effective removal of malachite green (MG) and methyl orange (MO) dyes. The optimization of the nanocomposite's performance was carried out using response surface methodology (RSM). The adsorption characteristics were further evaluated through isotherm models, kinetic studies and thermodynamic analyses. The mesoporous nature of TO@CTAB was confirmed through BET analysis, revealing a pore diameter of 4.625 nm. The crystalline size of TO@CTAB is 54.78 nm, and its crystalline index is 70.84%. The optimal operating conditions were established based on the results obtained from the ANOVA. The Langmuir isotherm model demonstrates superior adsorption performance compared to the Freundlich isotherm model, with adsorption efficiencies of 317.46 mg/g for MO and 306.748 mg/g for MG. The pseudo-second-order model, with an R 2 value of 0.998 and 0.997 for MO and MG, respectively, provides a more accurate and reliable explanation of the adsorption process compared to the pseudo-first-order model. Furthermore, the high reusability and minimal deterioration of TO@CTAB were observed for up to 5 cycles. The analysis of the adsorption mechanism indicates that the adsorption of MG and MO occurs through H-bonding, electrostatic and π-π interactions. A comprehensive cost analysis of the process was conducted to evaluate the cost-effectiveness; total expenditure incurred during the process was determined to be within acceptable limits. TO@CTAB was assessed using real wastewater samples, demonstrating a decolourization efficiency of 82%. Additionally, it resulted in a reduction of COD, BOD, TSS and TDS.
Competing Interests: Declarations Ethics approval Not applicable to the current study. Consent for publication The authors express their consent for the publication of research work. Competing interests The authors declare no competing interests.
(© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)
Databáze: MEDLINE
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