Cobalt-Catalyzed Regioselective C8-H Sulfoxamination of 1-Naphthylamine Derivatives with NH-Sulfoximines.

Autor:	Rathod NB; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Patel RN; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Patel SD; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Patel DM; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Sonawane MA; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Thakur DG; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India., Ghosh SC; Natural Products and Green Chemistry Division, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364002, Gujarat, India.; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
Jazyk:	angličtina
Zdroj:	The Journal of organic chemistry [J Org Chem] 2024 Dec 20; Vol. 89 (24), pp. 18436-18444. Date of Electronic Publication: 2024 Nov 18.
DOI:	10.1021/acs.joc.4c02318
Abstrakt:	A simple cobalt-catalyzed, picolinamide-directed C8-H sulfoxamination of 1-naphthalamides with NH-sulfoximines has been developed. This cross-dehydrogenative C-H/N-H coupling reaction offers a facile route to N-arylated sulfoximines, exhibiting high yields, a broad substrate scope, and excellent functional group tolerance and scalability.
Databáze:	MEDLINE
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