A Novel Fluorescent Chemosensor for Sensitive and Rapid Determination of Pb(II) Ions in Aqueous Environments.

Autor: Çubuk S; Department of Chemistry, Faculty Science, Marmara University, Istanbul, 34722, Türkiye. sonercubuk@marmara.edu.tr., Salah N; Department of Chemistry, Faculty Science, Marmara University, Istanbul, 34722, Türkiye., Nallbani BG; Faculty of Pharmacy, UBT - Higher Education Institution, Lagjia Kalabria, Prishtina, 10000, Republic of Kosovo., Yetimoğlu EK; Department of Chemistry, Faculty Science, Marmara University, Istanbul, 34722, Türkiye., Kahraman MV; Department of Chemistry, Faculty Science, Marmara University, Istanbul, 34722, Türkiye.
Jazyk: angličtina
Zdroj: Journal of fluorescence [J Fluoresc] 2024 Nov 16. Date of Electronic Publication: 2024 Nov 16.
DOI: 10.1007/s10895-024-04034-8
Abstrakt: This investigation devised an eco-friendly spectrofluorometric Pb(II) ion measurement approach. To determine Pb(II) ions, a polymeric fluorescence sensor membrane with excellent selectivity has been developed. It contains photoinitiators, functional monomers that can be cured under UV radiation, and cross-linking agents. After the characterization of the membrane, the most suitable parameters for the measurement of Pb(II) ions were determined. The measurement was performed in a short time-roughly 40 s-at emission and excitation wavelengths of 488 nm and 277 nm, respectively, at pH 6.0. The developed method's detection limit was calculated as 1.42 × 10 - 9 mol L - 1 , and its calibration range was recorded as 4.83 × 10 - 9 to 9.66 × 10 - 8 mol L - 1 . Recovery studies and the sensor's stability, lifetime, and repeatability have been evaluated. Real sample applications have been implemented using wastewater samples. The suggested approach may be used to quickly and accurately determine Pb(II) ions at low concentrations with good selectivity and sensitivity.
Competing Interests: Declarations Ethical Approval Not applicable. Consent to Participate Not applicable. Consent for Publication Not applicable. Competing Interests The authors declare no competing interests.
(© 2024. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.)
Databáze: MEDLINE
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