Heavy Pentaisopropylcyclopentadienyltriylenes and their Heterobimetallic Complexes.

Autor: Bischoff IA; Department of Chemistry; Faculty of Natural Sciences and Technology, Saarland University Campus Saarbrücken, 66123, Saarbrücken, Saarland, Germany., Morgenstern B; Department of Chemistry; Faculty of Natural Sciences and Technology, Saarland University Campus Saarbrücken, 66123, Saarbrücken, Saarland, Germany., Zimmer M; Department of Chemistry; Faculty of Natural Sciences and Technology, Saarland University Campus Saarbrücken, 66123, Saarbrücken, Saarland, Germany., Schäfer A; Department of Chemistry; Faculty of Natural Sciences and Technology, Saarland University Campus Saarbrücken, 66123, Saarbrücken, Saarland, Germany.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Nov 14, pp. e202419688. Date of Electronic Publication: 2024 Nov 14.
DOI: 10.1002/anie.202419688
Abstrakt: A series of triylenes of the heavy group 13 elements gallium, indium and thallium, carrying the pentaisopropylcyclopentadienyl ligand is reported. The compounds were characterized in solution and in the solid-state and their donor ligand properties in heterobimetallic complexes were investigated, whereby a series of tungsten carbonyl complexes was isolated. Furthermore, a new synthetic route towards a previously described lithium-aluminum heterobimetallic dimetallocene is reported, which also enabled the isolation of a heterobimetallic polydecker of lithium and gallium.
(© 2024 The Author(s). Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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