Basics and Advances of Manganese-Based Cathode Materials for Aqueous Zinc-Ion Batteries.

Autor: Hashem Abdelmohsen A; Institute for Energy Research, School of Material Science and Engineering, Jiangsu University, Zhenjiang, 212013, Jiangsu, China NOT applicable.; The Central Laboratory, Faculty of Postgraduate Studies for Advanced Science (PSAS), Beni-Suef University, Beni-Suef, 62511, Egypt NOT applicable., El-Khodary SA; Institute for Energy Research, School of Material Science and Engineering, Jiangsu University, Zhenjiang, 212013, Jiangsu, China NOT applicable.; Building Physics and Environment Institute, Housing & Building National Research Center (HBRC), Dokki, Cairo 12311, Egypt NOT applicable., Ismail N; Physical Chemistry Department, Centre of Excellence for Advanced Sciences, Renewable Energy Group, National Research Centre, 12311 Dokki, Giza, Egypt., Song Z; Institute for Energy Research, School of Material Science and Engineering, Jiangsu University, Zhenjiang, 212013, Jiangsu, China NOT applicable., Lian J; Institute for Energy Research, School of Material Science and Engineering, Jiangsu University, Zhenjiang, 212013, Jiangsu, China NOT applicable.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Nov 12, pp. e202403425. Date of Electronic Publication: 2024 Nov 12.
DOI: 10.1002/chem.202403425
Abstrakt: It is greatly crucial to develop low-cost energy storage candidates with high safety and stability to replace alkali metal systems for a sustainable future. Recently, aqueous zinc-ion batteries (ZIBs) have received tremendous interest owing to their low cost, high safety, wide oxidation states, and sophisticated fabrication process. Nanostructured manganese (Mn)-based oxides in different polymorphs are the potential cathode materials for the widespread application of ZIBs. However, Mn-based oxide materials suffer from several drawbacks, such as low electronic/ionic conductivity and poor cycling performance. To overcome these issues, various structural modification strategies have been adopted to enhance their electrochemical activity, including phase/defect engineering, doping with foreign atoms (e. g., metal and/or nonmetal atoms), and coupling with carbon materials or conducting polymers. Herein, this review targets to summarize the advantages and disadvantages of the above-mentioned strategies to improve the electrochemical performance of the cathodic part of ZIBs. The challenges and suggestions for the development of manganese oxides for ZIBs are put forward.
(© 2024 Wiley-VCH GmbH.)
Databáze: MEDLINE
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