Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant.

Autor: Quon AS; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., Manriquez D; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., Nguyen A; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., Papazyan EK; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., Wijeratne P; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., An L; U.S. DOE Ames National Laboratory, Iowa State University, Ames, Iowa 50011, USA., Qi L; U.S. DOE Ames National Laboratory, Iowa State University, Ames, Iowa 50011, USA., Tang MJ; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu., Ready AD; Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA., Farha OK; Department of Chemistry and International Institute for Nanotechnology (IIN) and Department of Chemical & Biological Engineering, Northwestern University, Evanston, Illinois 60208, USA. o-farha@northwestern.edu., Liu Y; Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA. yliu114@calstatela.edu.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Nov 05. Date of Electronic Publication: 2024 Nov 05.
DOI: 10.1039/d4cc03890h
Abstrakt: Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH 2 (Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.
Databáze: MEDLINE