Heavier Diferrocenylpnictogenium Ions.

Autor: Stoian C; Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359, Bremen, Germany., Olaru M; Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359, Bremen, Germany., Demeshko S; Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, 37077, Göttingen, Germany., Fischer M; Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, 37077, Göttingen, Germany., Mebs S; Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195, Berlin, Germany., Hupf E; Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359, Bremen, Germany., Beckmann J; Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359, Bremen, Germany.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Oct 29, pp. e202403555. Date of Electronic Publication: 2024 Oct 29.
DOI: 10.1002/chem.202403555
Abstrakt: The synthesis, characterization and reactivity of the diferrocenylphosphenium ion [Fc 2 P] + was extended to the heavier diferrocenylpnictogenium ions, [Fc 2 E] + (E=As, Sb, Bi). The lighter diferrocenylnitrenium ion, [Fc 2 N] + , was detected by mass spectrometry, but could not be isolated. The molecular structures of [Fc 2 E] + (E=P, As, Sb, Bi) reveal intramolecular coordination of the iron atoms, which counterbalance the electron deficiency of the pnictogens without affecting the strong Lewis acidities, which were determined according to the method of Gutmann and Beckett. The (electro-)chemical oxidation and reduction afforded the dications [Fc 2 E] 2+ (E=P (unstable), As) and the neutral dipnictogens Fc 2 EEFc 2 (E=P, As).
(© 2024 The Author(s). Chemistry - A European Journal published by Wiley-VCH GmbH.)
Databáze: MEDLINE
Externí odkaz: