Quantitative analysis of air-oxidation reactions of thiolate-protected gold nanoclusters.

Autor: Suzuki W; Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan teranisi@scl.kyoto-u.ac.jp., Takahata R; Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan teranisi@scl.kyoto-u.ac.jp.; Graduate School for Science, Kyoto University Uji Kyoto 611-0011 Japan., Mizuhata Y; Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan teranisi@scl.kyoto-u.ac.jp.; Graduate School for Science, Kyoto University Uji Kyoto 611-0011 Japan.; Integrated Research Consortium on Chemical Sciences Uji Kyoto 611-0011 Japan., Tokitoh N; Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan teranisi@scl.kyoto-u.ac.jp.; Graduate School for Science, Kyoto University Uji Kyoto 611-0011 Japan.; Integrated Research Consortium on Chemical Sciences Uji Kyoto 611-0011 Japan., Xue S; School of Chemistry and Chemical Engineering, Jiangsu University 301 Xuefu Road Zhenjiang 212013 China., Teranishi T; Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan teranisi@scl.kyoto-u.ac.jp.; Graduate School for Science, Kyoto University Uji Kyoto 611-0011 Japan.
Jazyk: angličtina
Zdroj: Chemical science [Chem Sci] 2024 Oct 17. Date of Electronic Publication: 2024 Oct 17.
DOI: 10.1039/d4sc02995j
Abstrakt: The interaction of dioxygen (O 2 ) with inorganic nanomaterials is one of the most essential steps to understanding the reaction mechanism of O 2 -related reactions. However, quantitative analyses for O 2 -binding processes and subsequent oxidation reactions on the surface are still elusive, whereas the reaction of O 2 with molecules such as transition metal complexes has been widely explored. Herein, we have quantitatively evaluated reaction processes of air-oxidation reactions of atomically precise thiolate-protected Au 25 nanoclusters ([Au 25 (SR) 18 ] - ) as a model of O 2 activation by inorganic nanomaterials. Kinetic analyses on the air-oxidation reaction of [Au 25 (SR) 18 ] - revealed a controlling factor for O 2 -activation processes, which could be finely tunable by the protecting thiolate ligands.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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