Construction of covalent organic frameworks via the Mannich reaction at room temperature for light-driven oxidative hydroxylation of arylboronic acids.

Autor: Wang JC; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Sun T; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Zhang J; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Chen Z; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Du JQ; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Kan JL; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn., Dong YB; College of Chemistry, Chemical Engineering and Materials Science, Collaborative, Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University Jinan 250014 P. R. China wangjiancheng1003@163.com yubindong@sdnu.edu.cn.
Jazyk: angličtina
Zdroj: Chemical science [Chem Sci] 2024 Oct 17. Date of Electronic Publication: 2024 Oct 17.
DOI: 10.1039/d4sc04358h
Abstrakt: An increasing variety of organic reactions have been developed for the synthesis of more structurally stable and multifunctional COFs. Here, we report a class of β-ketamine linked covalent organic frameworks that were constructed through the CeCl 3 -catalyzed multi-component Mannich reaction at room temperature. And the TAD-COF obtained based on this method could significantly promote the light-driven oxidative hydroxylation of arylboronic acids.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE