Engineering of Single-Atomic Sites for Electro- and Photo-Catalytic H 2 O 2 Production.

Autor: Li Y; Department of Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, 999077, China., Luan D; Department of Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, 999077, China., Lou XWD; Department of Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, 999077, China.
Jazyk: angličtina
Zdroj: Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2024 Oct 25, pp. e2412386. Date of Electronic Publication: 2024 Oct 25.
DOI: 10.1002/adma.202412386
Abstrakt: Direct electro- and photo-synthesis of H 2 O 2 through the 2e - O 2 reduction reaction (ORR) and H 2 O oxidation reaction (WOR) offer promising alternatives for on-demand and on-site production of this chemical. Exploring robust and selective active sites is crucial for enhancing H 2 O 2 production through these pathways. Single-atom catalysts (SACs), featuring isolated active sites on supports, possess attractive properties for promoting catalysis and unraveling catalytic mechanisms. This review first systematically summarizes significant advancements in atomic engineering of both metal and nonmetal single-atom sites for electro- and photo-catalytic 2e - ORR to H 2 O 2 , as well as the dynamic behaviors of active sites during catalytic processes. Next, the progress of single-atom sites in H 2 O 2 production through 2e - WOR is overviewed. The effects of the local physicochemical environments on the electronic structures and catalytic behaviors of isolated sites, along with the atomic catalytic mechanism involved in these H 2 O 2 production pathways, are discussed in detail. This work also discusses the recent applications of H 2 O 2 in advanced chemical transformations. Finally, a perspective on the development of single-atom catalysis is highlighted, aiming to provide insights into future research on SACs for electro- and photo-synthesis of H 2 O 2 and other advanced catalytic applications.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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