Zig-zag-fused π-extended BODIPYs via gold-catalysed cycloisomerisation.

Autor:	Ohashi F; Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan. htakano@chembio.nagoya-u.ac.jp., Takano H; Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan. htakano@chembio.nagoya-u.ac.jp.; Institute for Advanced Research, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601, Japan., Shinokubo H; Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan. htakano@chembio.nagoya-u.ac.jp.
Jazyk:	angličtina
Zdroj:	Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Nov 01; Vol. 60 (88), pp. 12892-12895. Date of Electronic Publication: 2024 Nov 01.
DOI:	10.1039/d4cc04416a
Abstrakt:	π-Extension of the BODIPY core is an effective strategy to modulate the physical properties of BODIPYs. However, π-extension on the zig-zag edge of BODIPYs remains unexplored. Here, we disclose the synthesis of zig-zag-fused BODIPYs through gold-catalysed cycloisomerisation. The obtained BODIPYs show fascinating photophysical properties including near-infrared absorption and emission.
Databáze:	MEDLINE
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