Electrochemical, surface, and theoretical investigations of palm kernel shell extract as an effective inhibitor for carbon-steel corrosion in 1 M HCl solution.

Autor: Sanni O; Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology, University of Pretoria, Pretoria, 0002, South Africa. tayo.sanni@yahoo.com., Ren J; Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology, University of Pretoria, Pretoria, 0002, South Africa., Jen TC; Department of Mechanical Engineering Science, University of Johannesburg, Cnr Kingsway and University Roads, Johannesburg, 2092, South Africa.
Jazyk: angličtina
Zdroj: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2024 Oct 08. Date of Electronic Publication: 2024 Oct 08.
DOI: 10.1007/s11356-024-35159-9
Abstrakt: Herein, we employed palm kernel shell extract (PKSE) as an eco-friendly inhibitor for carbon steel in acidic-induced corrosion. The corrosion inhibition of PKSE on carbon steel in 1 M HCI solution was investigated by electrochemical impedance spectroscopy, weight loss, and potentiodynamic polarization measurements. The surface was characterized by scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy. Moreover, the elastic modulus and hardness tests were conducted. Weight loss measurements revealed that the optimum concentration of inhibitors is 500 ppm with 95.3% inhibition efficiency in 1 M HCl solution. Electrochemical results showed that the inhibitor could exhibit excellent corrosion inhibition performance and displayed mixed-type inhibition. The electrochemical impedance spectroscopy analysis shows that the inhibition performance increases by increasing the concentration of PKSE. The surface studies ensure the PKSE effectiveness in carbon steel surface damage reduction. Also, the adsorption of PKSE molecules on the carbon steel surface occurs according to the Langmuir isotherm model. The primary goal of this investigation was the utilization of palm kernel shell extract as corrosion inhibitor for 1018 low carbon steel in 1 M HCl solution, which highlights its novelty. The present results will be helpful to uncover the versatile importance of palm kernel shell compounds in the corrosion inhibition process.
(© 2024. The Author(s).)
Databáze: MEDLINE
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