| Autor: |
Kim M; Department of Food Engineering, Daegu University, Gyeongsan 38453, Republic of Korea., Kim TH; Analysis Technology and Tomorrow, Daegu 42703, Republic of Korea., Park JW; Analysis Technology and Tomorrow, Daegu 42703, Republic of Korea., Lee Y; Food Safety and Processing Research Division, National Institute Fisheries Science, Busan 46083, Republic of Korea., Jo MR; Food Safety and Processing Research Division, National Institute Fisheries Science, Busan 46083, Republic of Korea., Moon YS; Department of Horticulture and Life Science, Yeungnam University, Gyeongsan 38541, Republic of Korea., Im MH; Department of Food Engineering, Daegu University, Gyeongsan 38453, Republic of Korea. |
| Abstrakt: |
In this study, we developed and validated a multiresidue analytical method for the simultaneous detection of 24 pesticides in fishery products. Using the EN15662 extraction method and C 18 as the adsorbent for purification, the validation results complied with Codex guidelines, achieving recovery rates between 70% and 120% and relative standard deviation values (%RSD) within 20%, indicating excellent performance. The limit of detection ranged from 0.25 to 0.8 ng/kg, and the limit of quantification was between 3 and 10 ng/g, providing sufficient sensitivity to comply with future regulatory standards. The calibration curves for all 24 pesticides exhibited great linearity (R 2 > 0.98), also satisfying the Codex requirements. The matrix effect was less than 30% for some pesticides-within ±20%-indicating minimal interference from impurities. An analysis of 300 fishery samples from nine regions across South Korea detected lufenuron at 10 ng/g in eels; however, the risk assessment was below 0.19%, posing no significant hazard to public health. This newly developed analytical method proved effective for the multi-analysis of pesticide residues in fishery products, offering rapid and reliable monitoring of the import and export safety of fishery products. |
